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Barbier Polymerization-Induced Emission toward Organophosphorus-Containing
Clusteroluminescent Polymer with Aggregation-Induced Emission and
Photochromic Characteristics
Hong-Min Du (25157526)
Xi-Yao Gu (25157529)
Wen-Ming Wan (2201986)
Xiao-Li Sun (2048209)
Biophysics
Biochemistry
Physical Sciences not elsewhere classified
Pharmacology
Biotechnology
Evolutionary Biology
Chemical Sciences not elsewhere classified
Science Policy
Mental Health
Plant Biology
work therefore provides
efficient polymeric ligand
catalyzed kumada reaction
responsive pigment applications
responsive clusteroluminescent organophosphorus
polymer mainchain separately
responsive clusteroluminescent polymer
containing clusteroluminescent polymer
pot barbier polymerization
induced emission strategy
photochromic characteristics stimuli
containing polymer
photochromic characteristics
barbier polymerization
responsive moiety
induced emission
versatile strategy
smart materials
luminescent moiety
Stimuli-responsive
luminescent polymers hold great promise for
smart materials, which, however, suffer from complicated synthetic
procedures involving synthesis of stimuli-responsive moiety, luminescent
moiety and the polymer mainchain separately. Herein, we report a one-pot
Barbier polymerization-induced emission strategy to fabricate a stimuli-responsive
clusteroluminescent organophosphorus-containing polymer with intriguing
aggregation-induced emission and photochromic characteristics, involving
synchronous C–C and C–P bonds formation. An efficient
polymeric ligand for a nickel-catalyzed Kumada reaction and stimuli-responsive
pigment applications are demonstrated as well. This work therefore
provides a versatile strategy for the design of a stimuli-responsive
clusteroluminescent polymer.
2026-10-01T00:00:00Z
Text
Journal contribution
10.1021/acsmacrolett.6c00424.s001
https://figshare.com/articles/journal_contribution/Barbier_Polymerization-Induced_Emission_toward_Organophosphorus-Containing_Clusteroluminescent_Polymer_with_Aggregation-Induced_Emission_and_Photochromic_Characteristics/34047234
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