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Visible-Light-Induced
Dearomative Heteroarylation
of Anthracene Derivatives with Heteroarylnitriles via Combined Energy
Transfer and Electron Transfer
Zhao-Qin Sun (25150960)
Jia-Li Sui (16406454)
Yi-Qing Wang (5515640)
Xin-Yue Feng (25150963)
Saidan Xie (25150966)
Liwei Zhou (275029)
Zhen-Wei Luo (17735787)
Jin-Heng Li (1457626)
Xuan-Hui Ouyang (1457629)
Biochemistry
Space Science
Microbiology
Physiology
Evolutionary Biology
Chemical Sciences not elsewhere classified
Biological Sciences not elsewhere classified
Information Systems not elsewhere classified
Cancer
Infectious Diseases
Virology
radical anion intermediates
induced dearomative heteroarylation
especially pyridine rings
various polycyclic arenes
polycyclic compounds
high yields
heteroaryl groups
fluorescence properties
electron transfer
containing heterocycles
antimicrobial activities
anthracene derivatives
The introduction of nitrogen-containing
heterocycles,
especially
pyridine rings, into polycyclic compounds is expected to enhance their
antimicrobial activities and modulate their fluorescence properties.
A novel visible-light-induced dearomative heteroarylation of anthracenes
with cyanoarenes has been developed. Combining energy transfer processes
with electron transfer processes enables the generation of radical
anion intermediates, which could sequentially undergo radical–radical
coupling for the introduction of heteroaryl groups. This method was
compatible with various polycyclic arenes and cyanoarenes with excellent
functional group tolerance and high yields.
2026-09-30T00:00:00Z
Text
Journal contribution
10.1021/acs.orglett.6c03894.s001
https://figshare.com/articles/journal_contribution/Visible-Light-Induced_Dearomative_Heteroarylation_of_Anthracene_Derivatives_with_Heteroarylnitriles_via_Combined_Energy_Transfer_and_Electron_Transfer/34037887
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