<?xml version='1.0' encoding='utf-8'?>
<?xml-stylesheet type="text/xsl" href="/v2/static/oai2.xsl"?>
<OAI-PMH xmlns="http://www.openarchives.org/OAI/2.0/" xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/ http://www.openarchives.org/OAI/2.0/OAI-PMH.xsd">
  <responseDate>2026-10-13T21:00:13Z</responseDate>
  <request identifier="oai:figshare.com:article/34024592" metadataPrefix="oai_dc" verb="GetRecord">https://api.figshare.com/v2/oai</request>
  <GetRecord>
    <record>
      <header>
        <identifier>oai:figshare.com:article/34024592</identifier>
        <datestamp>2026-09-29T15:00:08Z</datestamp>
        <setSpec>category_1</setSpec>
        <setSpec>category_4</setSpec>
        <setSpec>category_7</setSpec>
        <setSpec>category_8</setSpec>
        <setSpec>category_12</setSpec>
        <setSpec>category_14</setSpec>
        <setSpec>category_15</setSpec>
        <setSpec>category_16</setSpec>
        <setSpec>category_21</setSpec>
        <setSpec>category_24</setSpec>
        <setSpec>category_272</setSpec>
        <setSpec>category_61</setSpec>
        <setSpec>category_106</setSpec>
        <setSpec>portal_63</setSpec>
        <setSpec>item_type_6</setSpec>
        <setSpec>month_year_09_2026</setSpec>
      </header>
      <metadata>
        <oai_dc:dc xmlns:xsi="http://www.w3.org/2001/XMLSchema-instance"  xmlns:oai_dc="http://www.openarchives.org/OAI/2.0/oai_dc/" xmlns:dc="http://purl.org/dc/elements/1.1/" xsi:schemaLocation="http://www.openarchives.org/OAI/2.0/oai_dc/ http://www.openarchives.org/OAI/2.0/oai_dc.xsd">
          <dc:title>Direct and
Reversible Esterification of a Phosphonic
Acid under Ambient Conditions through a Dissociative Mechanism</dc:title>
          <dc:creator>Christina
K. McCabe (25137467)</dc:creator>
          <dc:creator>YuXiang Wei (20572679)</dc:creator>
          <dc:creator>Marc-André Légaré (1593322)</dc:creator>
          <dc:subject>Biophysics</dc:subject>
          <dc:subject>Biochemistry</dc:subject>
          <dc:subject>Medicine</dc:subject>
          <dc:subject>Microbiology</dc:subject>
          <dc:subject>Cell Biology</dc:subject>
          <dc:subject>Molecular Biology</dc:subject>
          <dc:subject>Neuroscience</dc:subject>
          <dc:subject>Physiology</dc:subject>
          <dc:subject>Biotechnology</dc:subject>
          <dc:subject>Evolutionary Biology</dc:subject>
          <dc:subject>Environmental Sciences not elsewhere classified</dc:subject>
          <dc:subject>Developmental Biology</dc:subject>
          <dc:subject>Science Policy</dc:subject>
          <dc:subject>undergoes spontaneous condensation</dc:subject>
          <dc:subject>typical phosphonic acids</dc:subject>
          <dc:subject>phosphonic acid</dc:subject>
          <dc:subject>reversible esterification</dc:subject>
          <dc:subject>reaction suggest</dc:subject>
          <dc:subject>give monoesters</dc:subject>
          <dc:subject>dissociative mechanism</dc:subject>
          <dc:subject>ambient conditions</dc:subject>
          <dc:description>We report the synthesis of 1-dimethylaminonaphthyl-8-phosphonic
acid, which, in contrast with typical phosphonic acids, undergoes
spontaneous condensation with alcohols to give monoesters under ambient
conditions. The selectivity and reversibility of the reaction suggest
that it occurs through a dissociative mechanism, inaccessible to typical
phosphonic acids.</dc:description>
          <dc:date>2026-09-29T00:00:00Z</dc:date>
          <dc:type>Text</dc:type>
          <dc:type>Journal contribution</dc:type>
          <dc:identifier>10.1021/acs.inorgchem.6c03183.s001</dc:identifier>
          <dc:relation>https://figshare.com/articles/journal_contribution/Direct_and_Reversible_Esterification_of_a_Phosphonic_Acid_under_Ambient_Conditions_through_a_Dissociative_Mechanism/34024592</dc:relation>
          <dc:rights>CC BY-NC 4.0</dc:rights>
        </oai_dc:dc>
      </metadata>
    </record>
  </GetRecord>
</OAI-PMH>
