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oai:figshare.com:article/34018420 2026-09-28T20:14:44Z category_1 category_4 category_915 category_12 category_15 category_16 category_19 category_21 category_272 category_873 portal_63 item_type_6 month_year_09_2026

Dual-Functional Triphenylamine-Based Conjugated Porous Polymer for Visible-Light-Driven Photocatalysis and Rapid Reversible HCl Sensing Pritee (20349672) Preety Yadav (16699641) Shikha Sharma (141788) Sanjeeve Thakur (5153669) Biophysics Biochemistry Physical Sciences not elsewhere classified Cell Biology Neuroscience Physiology Pharmacology Biotechnology Environmental Sciences not elsewhere classified Chemical Sciences not elsewhere classified stiff aromatic aldehyde pronounced “ turn pronounced radical signal optical band gap including inert atmosphere good thermal stability fourier transform infrared elevated polymerization temperature electron paramagnetic resonance 333 ° c stringent experimental conditions achieves effective degradation 5 ″-( benzene state hcl sensors rhb upon visible ray photoelectron spectroscopy diffuse reflectance spectroscopy transport light energy high surface area 5 ’, 5 tta </ b visible color change 3 </ sub 2 </ sup surface area color change tta ), photocatalytic degradation ambient conditions g </ thermogravimetric analysis strong reversibility semiconducting behavior scale production reversible naked porous framework organic contaminants naked eye light exposure insights underscore imine moieties hcl vapors functional materials eye solid efficient formation Conjugated porous organic polymers (CPPs) have emerged as promising photocatalysts because of their high surface area and efficient ability to collect and transport light energy through their delocalized backbone. Nevertheless, their synthesis methods require expensive monomers, stringent experimental conditions, including inert atmosphere, elevated polymerization temperature, and the use of metals as catalysts. To overcome these limitations, a triphenylamine-based conjugated porous polymer (TPA-TTA) has been prepared through a one-pot Schiff base reaction in ambient conditions in the absence of a metal catalyst. In this synthesis, 5’,5,5″-(benzene-1,3,5-triyl)tris(thiophene-2-carbaldehyde) (TTA), a stiff aromatic aldehyde, was condensed with tris(4-aminophenyl) amine (TPA). Diffuse reflectance spectroscopy (DRS) analysis revealed an optical band gap of 2.01 eV, confirming its semiconducting behavior. Electron paramagnetic resonance (EPR) analysis exhibited a pronounced radical signal at g = 2.00, suggesting the efficient formation of free radicals upon visible-light exposure which can promote the photocatalytic degradation of organic contaminants. The Brunauer–Emmett–Teller (BET) analysis indicates that TPA-TTA has a porous framework with a surface area of 109.3 m2 g–1, while thermogravimetric analysis (TGA) demonstrates its good thermal stability up to 333 °C. Photocatalytic studies further show that TPA-TTA achieves effective degradation of 88.38, 91, 90.4, 94, 79.8, 82 and 95% for TC, HQ, PCM, MO, AMX, NR, and RHB upon visible-light exposure, respectively. Owing to the protonation of imine moieties in the polymeric framework upon exposure to HCl vapors, TPA-TTA exhibits a pronounced “turn-off” fluorescence response along with a rapid (2s) visible color change to the naked eye. The color change of TPA-TTA triggered by HCl vapors is fully reversible upon exposure to NH3 vapors, demonstrating its strong reversibility and reusability. The protonation–deprotonation mechanism was also supported by Fourier transform infrared (FTIR) spectroscopy and X-ray photoelectron spectroscopy (XPS) studies. These insights underscore the feasibility of large-scale production of metal-free conjugated porous polymers as dual-functional materials, serving as photocatalysts and reversible naked-eye solid-state HCl sensors. 2026-09-28T00:00:00Z Text Journal contribution 10.1021/acsapm.6c01926.s001 https://figshare.com/articles/journal_contribution/Dual-Functional_Triphenylamine-Based_Conjugated_Porous_Polymer_for_Visible-Light-Driven_Photocatalysis_and_Rapid_Reversible_HCl_Sensing/34018420 CC BY-NC 4.0