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        <identifier>oai:figshare.com:article/33971125</identifier>
        <datestamp>2026-09-23T05:49:47Z</datestamp>
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          <dc:title>Supplementary file 1_Observing system simulation experiment by integrating multi-source satellite observations.docx</dc:title>
          <dc:creator>Zheng Yufei (9290808)</dc:creator>
          <dc:creator>Bo Zhenyu (25094530)</dc:creator>
          <dc:creator>Sun Yubao (25094533)</dc:creator>
          <dc:creator>Zhang Miao (10267171)</dc:creator>
          <dc:creator>Guo Bumin (25094536)</dc:creator>
          <dc:creator>Feng Xuan (129437)</dc:creator>
          <dc:creator>Qi Xiang (2146690)</dc:creator>
          <dc:subject>Environmental Science</dc:subject>
          <dc:subject>Bayesian inversion</dc:subject>
          <dc:subject>CO2-to-NOx ratio</dc:subject>
          <dc:subject>ffCO2</dc:subject>
          <dc:subject>OCO-2/3</dc:subject>
          <dc:subject>satellite remote sensing</dc:subject>
          <dc:subject>TROPOMI NO2</dc:subject>
          <dc:subject>WRF-STILT</dc:subject>
          <dc:description>&lt;p&gt;Fine-scale monitoring of urban fossil-fuel CO&lt;sub&gt;2&lt;/sub&gt; (ffCO&lt;sub&gt;2&lt;/sub&gt;) emissions is essential for evaluating mitigation policies and improving carbon accounting systems. Using Dongying, Shandong Province, as a case study, we developed an urban ffCO&lt;sub&gt;2&lt;/sub&gt; inversion framework that integrates TROPOMI NO&lt;sub&gt;2&lt;/sub&gt; observations, OCO-2/3 XCO&lt;sub&gt;2&lt;/sub&gt; observations and WRF-STILT transport simulations. First, a 5 km NO&lt;sub&gt;x&lt;/sub&gt; flux field was constructed from 2021 TROPOMI NO&lt;sub&gt;2&lt;/sub&gt; column densities and WRF wind fields using the flux-divergence method. Monthly prior CO&lt;sub&gt;2&lt;/sub&gt;-to-NO&lt;sub&gt;x&lt;/sub&gt; ratios were then derived from the GEMS inventory and used to convert NO&lt;sub&gt;x&lt;/sub&gt; fluxes into prior ffCO&lt;sub&gt;2&lt;/sub&gt; fluxes. Finally, OCO-2/3 observations and XSTILT column footprints were combined in a Bayesian inversion to optimize the CO&lt;sub&gt;2&lt;/sub&gt;-to-NO&lt;sub&gt;x&lt;/sub&gt; ratio and derive the posterior ffCO&lt;sub&gt;2&lt;/sub&gt; flux field. The TROPOMI-derived NO&lt;sub&gt;x&lt;/sub&gt; fluxes showed strong spatial heterogeneity in Dongying, with the highest values concentrated around Dongying Port, coastal oil and gas extraction areas and petrochemical industrial parks. The urban area showed lower but clearly structured emissions. The prior monthly CO&lt;sub&gt;2&lt;/sub&gt;-to-NO&lt;sub&gt;x&lt;/sub&gt; ratios were stable, ranging from 954.02 to 961.93, whereas the posterior ratios constrained by six OCO-2/3 overpasses ranged from 753 to 987, with a mean of 856.5. The resulting posterior ffCO&lt;sub&gt;2&lt;/sub&gt; emission estimate for Dongying was 45.7 Mt yr-1, with a range of 40.2–52.7 Mt yr-1. These results show that the joint use of NO&lt;sub&gt;2&lt;/sub&gt; and CO&lt;sub&gt;2&lt;/sub&gt; satellite observations can constrain both the spatial structure and magnitude of urban ffCO&lt;sub&gt;2&lt;/sub&gt; emissions, providing a methodological reference for carbon emission accounting in industrial cities.&lt;/p&gt;</dc:description>
          <dc:date>2026-09-23T05:49:47Z</dc:date>
          <dc:type>Dataset</dc:type>
          <dc:type>Dataset</dc:type>
          <dc:identifier>10.3389/fenvs.2026.1950661.s001</dc:identifier>
          <dc:relation>https://figshare.com/articles/dataset/Supplementary_file_1_Observing_system_simulation_experiment_by_integrating_multi-source_satellite_observations_docx/33971125</dc:relation>
          <dc:rights>CC BY 4.0</dc:rights>
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