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        <identifier>oai:figshare.com:article/33966184</identifier>
        <datestamp>2026-09-22T16:17:40Z</datestamp>
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          <dc:title>Superionic Helium in Mg&lt;sub&gt;2&lt;/sub&gt;SiO&lt;sub&gt;4&lt;/sub&gt;He&lt;sub&gt;2&lt;/sub&gt; at Ultrahigh Pressure: Implications for Delayed Cooling of Hot Jupiters</dc:title>
          <dc:creator>Wenxuan Chen (2832497)</dc:creator>
          <dc:creator>Shumin Guo (12995318)</dc:creator>
          <dc:creator>Chengda Li (21249688)</dc:creator>
          <dc:creator>Yingze Wang (6095966)</dc:creator>
          <dc:creator>Jialing Cai (11579362)</dc:creator>
          <dc:creator>Guiyan Dong (21510281)</dc:creator>
          <dc:creator>Yangfan Guo (17330673)</dc:creator>
          <dc:creator>Simon Redfern (492498)</dc:creator>
          <dc:creator>Defang Duan (13154257)</dc:creator>
          <dc:subject>Planetary science (excl. solar system and planetary geology)</dc:subject>
          <dc:subject>Structural properties of condensed matter</dc:subject>
          <dc:subject>helium-bearing magnesium silicate</dc:subject>
          <dc:subject>high-pressure compounds</dc:subject>
          <dc:subject>hot-Jupiter interiors</dc:subject>
          <dc:subject>planetary radius inflation</dc:subject>
          <dc:subject>superionic helium</dc:subject>
          <dc:description>&lt;p dir="ltr"&gt;The radius inflation of hot Jupiters remains a long-standing puzzle. Existing explanations invoke physical heating or delayed cooling through enhanced atmospheric opacity or inhibited convection, yet the possible role of reactions between volatiles and silicates under extreme conditions has received little attention. Here we predict a previously unknown compound, Mg&lt;sub&gt;2&lt;/sub&gt;SiO&lt;sub&gt;4&lt;/sub&gt;He&lt;sub&gt;2&lt;/sub&gt;, that becomes thermodynamically stable above 577 GPa, exhibits superionic helium diffusion at high temperature, and has thermal conductivity approximately one-quarter that of Mg&lt;sub&gt;2&lt;/sub&gt;SiO&lt;sub&gt;4&lt;/sub&gt;. Its formation at hot Jupiter core-mantle boundaries sequesters helium into the silicate, creating a compositionally stratified, insulating thermal boundary layer that delays planetary cooling, a chemical mechanism complementing existing models of radius inflation. Our results provide new constraints on the chemical environment and thermal evolution of giant exoplanetary interiors.&lt;/p&gt;&lt;p&gt;&lt;br&gt;&lt;/p&gt;</dc:description>
          <dc:date>2026-09-22T16:17:40Z</dc:date>
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          <dc:identifier>10.6084/m9.figshare.33966184.v1</dc:identifier>
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          <dc:rights>CC BY 4.0</dc:rights>
          <dc:rights>Open Access after 2027-03-22</dc:rights>
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