2026-10-07T04:58:34Z https://api.figshare.com/v2/oai

oai:figshare.com:article/33935155 2026-09-18T13:03:15Z portal_1197 item_type_3 month_year_09_2026

Data for Oxidation of 5‐hydroxymethyl furfural to 2,5‐furan dicarboxylic acid under mild aqueous conditions catalysed by MIL‐100(Fe) metal‐organic framework Thomas W. Chamberlain (1355565) Volkan Degirmenci (2035699) Richard I. Walton (1328463) Metal-organic frameworks Oxidation Biomass Furans -- Oxidation Migrated from ePrints We present the use of the redox active MIL-100(Fe) metal-organic framework (MOF) as a catalyst for the oxidation of 5-hydroxymethyl furfural (HMF) into 2,5-furan dicarboxylic acid (FDCA) in water. The MOF is synthesised in water alone under mild hydrothermal conditions and 1H NMR is used to analyse the products of HMF oxidation. The MOF in combination with the co-catalyst TEMPO provides a total selectivity of desired products of 74% with a maximum FDCA yield of 57% seen after 24 hours at only 70 °C. The catalyst is recycled five times with no loss in activity and no evidence of a reduction to the crystallinity of the MOF.<br><br>All data are ascii format and are labelled according to the figures in the paper. Figure 1B: Powder XRD data. Two-columns: diffraction angle (two-theta) and intensity. Figure S2: TGA data. Two-columns: temperature (degrees Celsius) and % mass. Figure S8: Powder XRD data. Two-columns: diffraction angle (two-theta) and intensity. Figure S11: Nitrogen adsorption data. Two columns: energy and normalised absorption. 2022-01-27T00:00:00Z Dataset Dataset 10.82444/warw.33935155.v1 https://figshare.com/articles/dataset/Data_for_Oxidation_of_5_hydroxymethyl_furfural_to_2_5_furan_dicarboxylic_acid_under_mild_aqueous_conditions_catalysed_by_MIL_100_Fe_metal_organic_framework/33935155 CC BY 4.0