2026-10-14T11:20:46Z https://api.figshare.com/v2/oai

oai:figshare.com:article/33820696 2026-09-15T19:57:35Z portal_1197 item_type_3 month_year_09_2026

Data for Asymmetric transfer hydrogenation of unsaturated ketones; factors influencing 1,4- vs 1,2- regio- and enantioselectivity, and alkene vs alkyne directing effects Thomas Howard Hall (24855997) Hannah Adams (24951052) Vijyesh K. Vyas (10708795) K. L. Michael Chu (24954349) Martin Wills (1301133) Hydrogenation Ketones -- Synthesis Ruthenium catalysts Migrated from ePrints A detailed study has been completed on the asymmetric transfer hydrogenation (ATH) of a series of enones using Ru(II) catalysts. Electron-rich rings adjacent to the Cdouble bondO group reduce the level of Cdouble bondO reduction compared to Cdouble bondC. The ATH reaction can readily discriminate between double and triple bonds adjacent to ketones, reducing the double bond but leaving a triple bond intact in the major product.<br><br>Data record is empty. 2026-09-15T19:57:35Z Dataset Dataset 10.82444/warw.33820696.v1 https://figshare.com/articles/dataset/Data_for_Asymmetric_transfer_hydrogenation_of_unsaturated_ketones_factors_influencing_1_4-_vs_1_2-_regio-_and_enantioselectivity_and_alkene_vs_alkyne_directing_effects/33820696 CC BY 4.0