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oai:figshare.com:article/33797230 2026-09-15T13:49:35Z portal_1197 item_type_3 month_year_09_2026

Data for UV irradiation of Cu-based complexes with aliphatic amine ligands as used in living radical polymerization Evelina Liarou (4729302) Michael Staniforth (1323402) James Town (11262782) Arkadios Marathianos (10866087) Maria Grypioti (24939043) Yongguang Li (514020) Yujing Chang (18953281) Spyridon Efstathiou (8816882) Ellis Hancox (14276126) Alan M. Wemyss (5897366) Paul Wilson (146891) Bryn Jones (300416) Mohammed Aljuaid (10491922) Vasilios G. Stavros (1263888) David M. Haddleton (1273797) Ultraviolet radiation Ultraviolet radiation -- Physiological effect Polymerization Photochemistry Migrated from ePrints The effect UV irradiation on Cu(II)-based complexes with aliphatic amine ligands is investigated. Four aliphatic amines are used as ligands and Cu(II)Br2 as the metal source for the formation of catalyst complexes that can be used for the photoinduced Cu-RDRP of methyl acrylate. Different characterization techniques such as transient electronic absorption spectroscopy (TEAS), ultraviolet-visible (UV-Vis) spectroscopy, electrospray ionization time of flight mass spectrometry (ESI-ToF-MS) and cyclic voltammetry (CV) are applied in order to provide insights into the catalyst behaviour upon photo-irradiation. The excited-state dynamics, the electrochemical behaviour of the Cu(II)/Cu(I) redox couples and the detection of different species upon complexation of the ligand to the metal center (before and after UV irradiation) are further depicted in the quality of the obtained polymers.<br><br>Experimental data presented in compressed (zipped) format containing 7 folders. Folder Structure: The files are organised by technique used for the characterisation of the final products. Abbreviations: NMR: Nuclear Magnetic Resonance GPC: Gel permeation chromatography ESI-ToF-MS: Electrospray Ionization-Time Of Flight (ESI-TOF) mass spectrometry (MS) UV-Vis: Ultraviolet-Visible Spectroscopy TEAS: Transient electronic absorption spectroscopy Software used : NMR : ACD labs GPC: Agilent GPC/SEC software (version A.02.01). ESI-ToF-MS: Bruker Analysis software UV-Vis: Agilent Cary UV software, plot through Origin 8.0 TEAS: Labview was used to collect the data, Excel and Origin was used to manipulate/plot the data, Glotaran was used to fit the data. 2019-12-12T00:00:00Z Dataset Dataset 10.82444/warw.33797230.v1 https://figshare.com/articles/dataset/Data_for_UV_irradiation_of_Cu-based_complexes_with_aliphatic_amine_ligands_as_used_in_living_radical_polymerization/33797230 CC BY 4.0