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oai:figshare.com:article/33791803 2026-09-15T12:16:18Z portal_1197 item_type_3 month_year_09_2026

Data for A hydrothermally stable ytterbium metal-organic framework as a bifunctional solid-acid catalyst for glucose conversion David Burnett (3842434) Ryan Oozeerally (2810392) Ralentri Pertiwi (24918970) Thomas W. Chamberlain (1355565) Nikolay Cherkasov (1735498) Guy J. Clarkson (1301127) Yuni Krisnandi (24932422) Volkan Degirmenci (2035699) Richard I. Walton (1328463) Glucose Ytterbium Heterogeneous catalysis Biomass conversion Migrated from ePrints Yb6(BDC)7(OH)4(H2O)4 contains both bridging hydroxyls and metal-coordinated waters, possessing Brønsted and Lewis acid sites. The material crystallises from water at 200 oC. Using the solid as a heterogenous catalyst, glucose is converted into 5-hydroxymethylfurfural, via fructose, with a total selectivity of ~70 % after 24 hours at 140 oC in water alone: the material is recyclable with no loss of crystallinity.<br><br>Data for Article "A Hydrothermally Stable Ytterbium Metal-Organic Framework as a Bifunctional Solid-Acid Catalyst for Glucose Conversion" Files contain the figure name in the paper and associated Electronic Supporting Information Powder XRD is 2-column ascii format angle (degrees two-theta), counts (arbitary units) TGA-DSC is 3 column ascii format temperature (degrees Celcius), percentage mass, heat flow (mW) In situ XRD is multi-column asci, with first column angle (degrees two-theta) and other colums counts (arbitary units) as per Figure S7 (bottom to top) TPD is 2-column ascii temperature (degrees Celcius), mass spectrum signal (arbitrary units) IR is 2-column ascii wavenumber (reciprocal centimetres), transmittance (normalised) 2019-08-15T00:00:00Z Dataset Dataset 10.82444/warw.33791803.v1 https://figshare.com/articles/dataset/Data_for_A_hydrothermally_stable_ytterbium_metal-organic_framework_as_a_bifunctional_solid-acid_catalyst_for_glucose_conversion/33791803 CC BY 4.0