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oai:figshare.com:article/33778798 2026-09-15T08:30:21Z portal_1197 item_type_3 month_year_09_2026

Data for Rhodium(III) complexes featuring coordinated CF3 appendages Jack Emerson-King (17863444) Ivan Prokes (1508173) Adrian B. Chaplin (1502605) Rhodium compounds Biphenyl compounds Migrated from ePrints The synthesis and characterisation of a homologous series of rhodium 2,2′‐biphenyl complexes featuring intramolecular dative bonding of the nominally inert and weakly coordinating trifluoromethyl group are described. Presence of these interactions is evidenced in the solid state using X‐ray diffraction, with Rh−F contacts of 2.36–2.45 Å, and in solution using NMR spectroscopy, through hindered C−CF3 bond rotation and the presence of time‐averaged 1JRhF and 2JPF coupling.<br><br>Rhodium(III) Complexes Featuring Coordinated CF3 Appendages. The primary analytical data is organised by new rhodium complex. Alphanumeric codes of the form JEK#_### are lab book. references. 2019-04-15T00:00:00Z Dataset Dataset 10.82444/warw.33778798.v1 https://figshare.com/articles/dataset/Data_for_Rhodium_III_complexes_featuring_coordinated_CF3_appendages/33778798 CC BY 4.0