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Data for An expanded MIL-53-type coordination polymer with a reactive pendant ligand Hannah Kunicki (24901027) Thomas W. Chamberlain (1355565) Guy J. Clarkson (1301127) Reza J. Kashtiban (1423762) Joseph E. Hooper (8486937) Daniel M. Dawson (1328457) Sharon E. Ashbrook (1328460) Richard I. Walton (1328463) Coordination polymers Organometallic compounds Ligands Migrated from ePrints A coordination polymer with a structure isoreticular to MIL-53, but containing a divalent metal cation (Co2+ or Mg2+) and a coordinating 4-styrylpyridine-N-oxide ligand, crystallises under solvothermal conditions; the pendant ligand can be brominated, with evidence from powder X-ray diffraction, element mapping and 81Br solid-state NMR for this post-synthesis modification.<br><br>Crystal structure are available from the CCDC using the information provided in the paper. Thermogravimetric analysis (TGA-DSC in Figure 3a) is provded in an ascii file in x,y1,y2 format: temperature, percentage mass, heat flow Measured powder XRD (Figure 4a) is provided in acsii files in x,y format: angle, intensity. 2018-07-03T00:00:00Z Dataset Dataset 10.82444/warw.33758200.v1 https://figshare.com/articles/dataset/Data_for_An_expanded_MIL-53-type_coordination_polymer_with_a_reactive_pendant_ligand/33758200 CC BY 4.0