2026-10-12T12:33:58Z
https://api.figshare.com/v2/oai
oai:figshare.com:article/33668875
2026-09-12T14:25:27Z
category_1
category_4
category_915
category_13
category_15
category_19
category_873
category_734
category_61
category_133
portal_63
item_type_3
month_year_09_2026
Chiral Anthranyl
Bis-sulfoxides with Modular Chiroptical
Properties Controlled by an Ionic Stimulus
Zhen Cao (30837)
Peizhao Liu (3794632)
Tiejun Li (438796)
Nicolas Vanthuyne (1426666)
Muriel Serradeil-Albalat (22423471)
Raphaël Méreau (1282401)
Emilie Pouget (1775755)
Brigitte Bibal (1695463)
Biophysics
Biochemistry
Physical Sciences not elsewhere classified
Genetics
Neuroscience
Pharmacology
Chemical Sciences not elsewhere classified
Biological Sciences not elsewhere classified
Developmental Biology
Plant Biology
sulfoxide receptors based
reversibly almost quenched
quantum chemical calculations
investigated using nmr
chiral anthranyl bis
ionic stimulus
cpl signals
cpl response
coordination complexes
chiroptical spectroscopies
New chiral fluorescent
bis-sulfoxide receptors based on <i>syn</i> and <i>anti</i> anthracene atropisomers were
synthesized. Their coordination complexes for silver(I), sodium(I),
and cesium(I) cations were investigated using NMR and chiroptical
spectroscopies as well as quantum chemical calculations. Notably,
the CPL signals of a pair of (<i>R</i>,<i>R</i>) and (<i>S</i>,<i>S</i>) <i>syn</i> atropisomers were reversibly almost quenched by CsBArF, enabling <i>in situ</i> nearly on/off modulation of the CPL response <i>via</i> an ionic stimulus.
2026-09-12T00:00:00Z
Dataset
Dataset
10.1021/acsomega.6c07072.s003
https://figshare.com/articles/dataset/Chiral_Anthranyl_Bis-sulfoxides_with_Modular_Chiroptical_Properties_Controlled_by_an_Ionic_Stimulus/33668875
CC BY-NC 4.0